منابع مشابه
Carboxylation of thin graphitic sheets is faster than that of carbon nanohorns.
Globular aggregates of carbon nanohorns (CNHs) often contain graphite-like thin sheets (GLSs), and providing different functions to CNHs and GLSs would expand the possible applications of the CNH-GLS aggregates. We show that the GLS edges can be carboxylated selectively by immersing the aggregates in an aqueous solution of H2O2 at room temperature for 1 hour. The presence of carboxyl groups was...
متن کاملPatterning Graphitic C-N Sheets into a Kagome Lattice for Magnetic Materials.
We propose porous C-N-based structures for biocompatible magnetic materials that do not contain even a single metal ion. Using first-principles calculations based on density functional theory, we show that when patterned in the form of a kagome lattice, nonmagnetic g-C3N4 not only becomes ferromagnetic but also its magnetic properties can be further enhanced by applying external strain. Similar...
متن کاملHalf-metallic and magnetic properties in nonmagnetic element embedded graphitic carbon nitride sheets.
We have investigated the structures, electronic structures and magnetic properties of the triazine-based g-C3N4 (gt-C3N4) monolayer doped with B, Al, and Cu atoms based on density functional theory using ab initio calculations. The B atom prefers to be situated at the center of the triazine ring, whereas the Al and Cu atoms tend to be located above the center of the triazine ring. The doping at...
متن کاملOne-step synthesis of nanocrystalline transition metal oxides on thin sheets of disordered graphitic carbon by oxidation of MXenes.
Herein we show that heating 2D Ti3C2 in air results in TiO2 nanocrystals enmeshed in thin sheets of disordered graphitic carbon structures that can handle extremely high cycling rates when tested as anodes in lithium ion batteries. Oxidation of 2D Ti3C2 in either CO2 or pressurized water also resulted in TiO2-C hybrid structures. Similarly, other hybrids can be produced, as we show here for Nb2...
متن کاملMonoatomic-thick graphitic carbon nitride dots on graphene sheets as an efficient catalyst in the oxygen reduction reaction.
Atomically thick two-dimensional materials have been increasingly attracting research interest not only due to their promising applications in a range of functional devices but also to their theoretical value to unraveling the catalytic electron transfer process within a simplified scenario. In this work, the monoatomic-thick dot-sized graphitic carbon nitride (g-C3N4) has been synthesized and ...
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ژورنال
عنوان ژورنال: Science
سال: 2020
ISSN: 0036-8075,1095-9203
DOI: 10.1126/science.369.6501.265-f